Short-range order in "disordered" aluminum solid solutions in ?-iron

نویسندگان

چکیده

The atomic structure of soft magnetic iron-aluminum alloys is studied by X-ray diffraction and nuclear gamma-resonance spectroscopy. concentration dependence the body-centered cubic lattice constant short-range order (SRO) parameters in region a disordered solid solution monitored. It shown that range from 3 to 18 at.% Al, increases almost linearly. Discrete decomposition gamma resonance spectra makes it possible determine such SRO as relative fractions contributions coordinations without Al atoms with one, two, three first second coordination shells. deviation values these average statistical probabilities indicates presence chemical arrangement atoms. largest deviations are observed at 12 15 Al. Conditions preliminary heat treatment, quenching paramagnetic state holding ferromagnetic state, give very similar parameters. method characterized high resolution hyperfine field, while having rather sensitivity for determining intensity individual Keywords: alloys, Fe-Al solution, local ordering, diffraction, Mossbauer effect, distribution over

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Short-range order in liquid aluminum chloride: ab initio molecular dynamics simulations and quantum-chemical calculations.

We use ab initio molecular dynamics simulations based on density-functional theory and quantum-chemistry calculations on molecular clusters to examine the structure of liquid AlCl3. In the past, conflicting descriptions of the short-range-order in molten AlCl3, based on either edge-sharing dimers or corner-sharing oligomers, have been proposed. This liquid also poses a simulation challenge, due...

متن کامل

Short-range order in ternary aUoy semiconductors

Atom arrangements in IH-V ternary aHoy semiconductors are discussed using a thermodynamic analysis in which the elastic strain caused by mixing is considered as the mixing enthalpy. In calculating the strain energy, both bond-stretching and bond-angl.e distortion are taken into account, and Martin's microscopic elastic constants are used. The results show that there is a preference for ordering...

متن کامل

Thermodynamic analysis of the short-range clustering in III V solid solutions

2014 An extension of the « D.L.P. » theory of Stringfellow taking clustering into account has been applied both to pseudobinary, pseudoternary and pseudoquaternary III V alloys. For alloys with two sites sublattices, this clustering tendency is introduced in each sublattice of the zinc blende through a positive short-range order parameter 03B1i-j depending on temperature and composition. It is ...

متن کامل

Determination of Short Range Order (sro) Parameters from Exafs Pair Distribution Functions of Oxide and Silicate Solid Solutions

Short Range Order (SRO) i n c e r t a i n s o l i d so lu t ions can be measured d i r e c t l y from observed EXAFS s t r u c t u r e f u n c t i o n peak areas. Results f o r MgO-FeO, MgO-Li FeO2, and CaMgSi O6 ~ a ~ e 2 + ~ i ~ 0 ~ so lu t ions i n d i c a t e t h a t these are almost completely d i sordere5 a t t h e i r synthesis temperatures. The necessi ty o f s t r u c t u r a l modelin...

متن کامل

Off-diagonal long-range order in solid 4He.

Measurements of the moment of inertia by Kim and Chan have found that solid (4)He acts like a supersolid at low temperatures. To understand the order in solid 4(He), we have used path integral Monte Carlo simulations to calculate the off-diagonal long-range order (ODLRO) [equivalent to Bose-Einstein condensation (BEC)]. We do not find ODLRO in a defect-free hcp crystal of (4)He at the melting d...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Fizika tverdogo tela

سال: 2023

ISSN: ['0367-3294', '1726-7498']

DOI: https://doi.org/10.21883/pss.2023.03.55576.558